Shibkovite Mineral Data

General Shibkovite Information

Chemical Formula:

K(Ca,Mn,Na)2(K2-x,[ ]x)2ZnSi12O30 (x~0.8)

Composition:

Molecular Weight = 1,180.17 gm

Potassium 7.29 % K 8.78 % K₂O

Sodium 0.58 % Na 0.79 % Na₂O

Calcium 4.41 % Ca 6.18 % CaO

Manganese 1.86 % Mn 2.40 % MnO

Zinc 16.62 % Zn 20.69 % ZnO

Silicon 28.56 % Si 61.09 % SiO₂

Oxygen 40.67 % O

______ ______

100.00 % 99.93 % = TOTAL OXIDE

Empirical Formula:

K_2.2Ca_1.3Mn²⁺_0.4Na_0.3Zn₃Si₁₂O₃₀

Environment:

Found in a boulder of perialkaline granitic pegmatite in moraine. A member of the Osumilite-Milarite group.

IMA Status:

Approved IMA 1998 (Dana # Added)

Locality:

Dara-i-Pioz glacier, Garmsky District, northern Tajikistan. Link to MinDat.org Location Data.

Name Origin:

Named after two prominent Russian geologists, Viktor Sergeevitch Shibkov (1926-1992) and Nikolai Viktorovitch Shibkov (1951-1991), who both spent their professional lives working on the geology of Soviet Asia.

Synonym:

ICSD 87953

IMA1997-018

PDF 51-1432

Shibkovite Image

Images:

Shibkovite Polylithionite

Comments: Clear crystalline shibkovite aggregates with peach colored translucent polylithionite.
Location: Dara-Pioz, Tien-Shan, Tadzhikistan. Scale: See Photo.
© Jeff Weissman / Photographic Guide to Mineral Species

Shibkovite Crystallography

Axial Ratios:

a:c = 1:1.3503

Cell Dimensions:

a = 10.505, c = 14.185, Z = 2; V = 1,355.66 Den(Calc)= 2.89

Crystal System:

Hexagonal - Dihexagonal Dipyramidal H-M Symbol (6/m 2/m 2/m) Space Group: P 6/mcc

$Help on X Ray Diffraction:$ X Ray Diffraction:

By Intensity(I/I_o): 3.83(1), 2.795(0.85), 3.345(0.6),

Physical Properties of Shibkovite

Cleavage:

None

Color:

Colorless, White.

Diaphaneity:

Transparent to Translucent

Fracture:

Brittle - Generally displayed by glasses and most non-metallic minerals.

Habit:

Microscopic Crystals - Crystals visible only with microscopes.

Hardness:

5.5-6 - Knife Blade-Orthoclase

Luster:

Vitreous (Glassy)

Streak:

white

Optical Properties of Shibkovite

Gladstone-Dale:

CI calc= 0.009 (Superior) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.1945,KC= 0.1962
Ncalc = 1.57

Optical Data:

Uniaxial (+), w=1.561, e=1.563, bire=0.0020.

Calculated Properties of Shibkovite

Electron Density:

Bulk Density (Electron Density)=2.84 gm/cc
note: Specific Gravity of Shibkovite =2.89 gm/cc.

Fermion Index:

Fermion Index = 0.02
Boson Index = 0.98

Photoelectric:

PE_Shibkovite= 10.97 barns/electron
U=PE_Shibkovite x r_electron= 31.11 barns/cc.

Radioactivity:

GRapi = 103.19 (Gamma Ray American Petroleum Institute Units)
Concentration of Shibkovite per GRapi unit = 0.97 (%)

Estimated Radioactivity from Shibkovite - barely detectable

Shibkovite Classification

Dana Class:

63.02.01a.16 (63)Cyclosilicate Condensed Rings

(63.02)6-membered rings

(63.02.01a)Milarite - Osumilite group (Milarite - Osumilite subgroup)

63.02.01a.01 Brannockite KSn2Li3Si12O30 P 6/mcc 6/m 2/m 2/m

63.02.01a.02 Chayesite K(Mg,Fe)4Fe(Si12O30) P 6/mcc 6/m 2/m 2/m

63.02.01a.03 Darapiosite KNa2Zr[Li(Mn,Zr)2Si12O30] P 6/mcc 6/m 2/m 2/m

63.02.01a.04 Eifelite KNa3Mg4Si12O30 P 6/mcc 6/m 2/m 2/m

63.02.01a.05 Merrihueite (K,Na)2(Fe,Mg)5Si12O30 P 6/mcc 6/m 2/m 2/m

63.02.01a.06 Osumilite-(Fe) (K,Na)(Fe,Mg)2(Al,Fe)3(Si,Al)12O30 P 6/mcc 6/m 2/m 2/m

63.02.01a.07 Osumilite-(Mg) (K,Na)(Mg,Fe)2(Al,Fe)3(Si,Al)12O30 P 6/mcc 6/m 2/m 2/m

63.02.01a.08 Poudretteite KNa2B3Si12O30 P 6/mcc 6/m 2/m 2/m

63.02.01a.09 Sugilite KNa2(Fe,Mn,Al)2Li3Si12O30 P 6/mcc 6/m 2/m 2/m

63.02.01a.10 Yagiite (Na,K)3Mg4(Al,Mg)6(Si,Al)24O60 P 6/mmc 6/m 2/m 2/m

63.02.01a.11 Dusmatovite K(K,Na,[])(Mn,Y,Zr)2(Zn,Li)3Si12O30 P 6/mcc 6/m 2/m 2/m

63.02.01a.12 Milarite K2Ca4Al2Be4Si24O60•(H2O) P 6/mcc 6/m 2/m 2/m

63.02.01a.13 Sogdianite (K,Na)2(Li,Fe,Al)3ZrSi12O30 P 6/mmm 6/m 2/m 2/m

63.02.01a.14 Roedderite (Na,K)2(Mg,Fe)5Si12O30 P 6₃/mmc 6/m 2/m 2/m

63.02.01a.15 Berezanskite! KLi3Ti2Si12O30 P 6/mcc 6/m 2/m 2/m

63.02.01a.16 Shibkovite! K(Ca,Mn,Na)2(K2-x,[]x)2ZnSi12O30(x~0.8) P 6/mcc 6/m 2/m 2/m

63.02.01a.17 Trattnerite! (Fe,Mg)2(Mg,Fe)3(Si12O30) P 6/mcc 6/m 2/m 2/m

63.02.01a.18 Almarudite! K([],Na)2(Mn,Fe,Mg)2(Be,Al)3[Si12O30] P 6/mcc 6/m 2/m 2/m

63.02.01a.19 Oftedalite! (Sc,Ca)2KBe3Si12O30 P 6/mmc 6/m 2/m 2/m

63.02.01a.20 Klochite ([]1Na1)KFe2Zn3[Si12O30] P 6/mcc 6/m 2/m 2/m

63.02.01a.21 Friedrichbeckeite! K([],Na)Mg2(Be2Mg)Si12O30 P 6/mcc 6/m 2/m 2/m

Strunz Class:

09.CM.05 09 - SILICATES (Germanates)

09.C - Cyclosilicates

09.CM -[Si6O18]12- 6-membered double rings (sechser-Doppelringe)

09.CM.05 Brannockite KSn2Li3Si12O30 P 6/mcc 6/m 2/m 2/m

09.CM.05 Armenite BaCa2Al6Si9O30•2(H2O) Pnc2 mm2

09.CM.05 Berezanskite! KLi3Ti2Si12O30 P 6/mcc 6/m 2/m 2/m

09.CM.05 Dusmatovite K(K,Na,[])(Mn,Y,Zr)2(Zn,Li)3Si12O30 P 6/mcc 6/m 2/m 2/m

09.CM.05 Chayesite K(Mg,Fe)4Fe(Si12O30) P 6/mcc 6/m 2/m 2/m

09.CM.05 Shibkovite! K(Ca,Mn,Na)2(K2-x,[]x)2ZnSi12O30(x~0.8) P 6/mcc 6/m 2/m 2/m

09.CM.05 Eifelite KNa3Mg4Si12O30 P 6/mcc 6/m 2/m 2/m

09.CM.05 Darapiosite KNa2Zr[Li(Mn,Zr)2Si12O30] P 6/mcc 6/m 2/m 2/m

09.CM.05 Merrihueite (K,Na)2(Fe,Mg)5Si12O30 P 6/mcc 6/m 2/m 2/m

09.CM.05 Roedderite (Na,K)2(Mg,Fe)5Si12O30 P 6₃/mmc 6/m 2/m 2/m

09.CM.05 Milarite K2Ca4Al2Be4Si24O60•(H2O) P 6/mcc 6/m 2/m 2/m

09.CM.05 Osumilite-(Fe) (K,Na)(Fe,Mg)2(Al,Fe)3(Si,Al)12O30 P 6/mcc 6/m 2/m 2/m

09.CM.05 Osumilite-(Mg) (K,Na)(Mg,Fe)2(Al,Fe)3(Si,Al)12O30 P 6/mcc 6/m 2/m 2/m

09.CM.05 Poudretteite KNa2B3Si12O30 P 6/mcc 6/m 2/m 2/m

09.CM.05 Sugilite KNa2(Fe,Mn,Al)2Li3Si12O30 P 6/mcc 6/m 2/m 2/m

09.CM.05 Sogdianite (K,Na)2(Li,Fe,Al)3ZrSi12O30 P 6/mmm 6/m 2/m 2/m

09.CM.05 Oftedalite! (Sc,Ca)2KBe3Si12O30 P 6/mmc 6/m 2/m 2/m

09.CM.05 Yagiite (Na,K)3Mg4(Al,Mg)6(Si,Al)24O60 P 6/mmc 6/m 2/m 2/m

09.CM.05 Trattnerite! (Fe,Mg)2(Mg,Fe)3(Si12O30) P 6/mcc 6/m 2/m 2/m

09.CM.05 Almarudite! K([],Na)2(Mn,Fe,Mg)2(Be,Al)3[Si12O30] P 6/mcc 6/m 2/m 2/m

Other Shibkovite Information

References:

NAME( CanMin, 8/99) PHYS. PROP.(MinRec, V 31, No. 2) OPTIC PROP.(MinRec, V 31, No. 2)

See Also:

Links to other databases for Shibkovite :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - GeoScienceWorld
4 - Google Images
5 - Google Scholar
6 - MinDAT
7 - Mineralienatlas (Deutsch)
8 - Online Mineral Museum
9 - QUT Mineral Atlas
10 - Ruff.Info

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Shibkovite

K(Ca,Mn,Na)2(K2-x,[ ]x)2ZnSi12O30 (x~0.8)
Dana No: 63.02.01a.16 Strunz No: 09.CM.05
Locality:

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